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Certainly some of the effect, regardless of the temperature of the water, is due to the fact that throwing it into the air spreads the water out and exposes more of its surface to the cold, allowing it to quickly freeze

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Nernst and Brunner incorporated Ficks first law of diffusion and modified the Noyes-Whitneys equation to: where, D = diffusion coefficient ( diffusivity ) of the drug A= surface area of the dissolving solid Kw/o = water/oil partition coefficient of the drug considering the fact that dissolution body fluids are aqueous