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Abbreviations -MSH -melanocyte-stimulating hormone ACTH adrenocorticotropic hormone cAMP cyclic adenosine monophosphate CAT catalase CREB cAMP response element-binding protein DHI 5,6-dihydroxyindole DHICA DHI-2- carboxylic acid ERK extracellular signal-regulated kinase GCL glutamate cysteine ligase GCLC GCL catalytic subunit GCLM GCL modifier subunit GPx glutathione peroxidase GR glutathione reductase GSH glutathione GSS glutathione synthetase GSSG glutathione disulphide GST glutathione S-transferase H 2 O 2 hydrogen peroxide JNK c-JUN N-terminal kinase L-DOPA L-3,4-dihydroxyphenylalanine MAPK mitogen-activated protein kinase MC1R melanocortin 1 receptor MITF melanogenesis-associated transcription factor NADPH nicotinamide adenine dinucleotide phosphate Nrf2 nuclear factor erythroid 2related factor 2 O 2 superoxide OH hydroxyl radical PKA protein kinase A POMC pro-opiomelanocortin ROS reactive oxygen species SCF stem cell factor SOD superoxide dismutase TCF-LEF T-cell factor/lymphoid enhancer-binding factor TRP-1 tyrosinase-related protein 1 TRP-2 dopachrome tautomerase Trx thioredoxin TrxR Trx reductase TYR tyrosinase UVR ultraviolet radiation Wnt wingless-related integration site xCT cystine/glutamate antiporter Contributor Information Kathryn F

In 2000, the United States National Library of Medicine created the web-based registry ClinicalTrials.gov for users to search the clinical trial information, including study design, methods, results, expected end dates, etc

The C201-harboring molecular shuttle is reminiscent of the mobile loops associated with cysteine persulfide transfer in Fe-S cluster protein biogenesis 29 and the mobile pantothenate arm of CoA persulfide reductases 17 except that here the enzyme shuttles a S -sulfonate moiety, an unprecedented finding

After binding for 10 min at 37C and separation of the bound complexes by centrifugation, the amounts of bound and free GST were determined by the Lowry method [29]

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Reference Carvalho-Moore, Norsworthy, Bonilha Piveta, Castner, Woolard and Arnold2022)