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doi:10.1016/j.conb.2019.12.003

Key to these findings was the modulation of intramolecular hydrogen bonding and lipophilicity, which improved passive diffusion across epithelial membranes

Theprincipal distinction between methyl-, ethyl-, andn-propyl-cobalamin lies in the relative stability of this MLCT state, with the terminal alkyl groups in ethyl and n-propyl acting as electron donors to destabilize the partial carbon anion in the MLCT state