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Current approaches To exemplify the issues surrounding prediction for cyclic 1,3-diketones using existing empirical approaches, the commercial program by ChemAxon known as Marvin was used to estimate values for a series of 1,3-CHD and 1,3-CPD derivatives ( o1 - o8 , tk1-tk15 and dk1 - dk12 shown in Supplementary Table 1 of the SI)